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Redox Chemistry

Topic 5 of 6

Make the electrodes part of the design

Copper electrodes behave differently from inert ones.

O-Level 6092 (2026) / SEC G3 K324 (2027)

Pure only
Pure only

Make the electrodes part of the design

Copper electrodes behave differently from inert ones.

To purify copper, use impure copper as the anode, pure copper as the cathode, and aqueous copper(II) sulfate as electrolyte. At the anode, Cu(s) -> Cu2+(aq) + 2e-. At the cathode, Cu2+(aq) + 2e- -> Cu(s). Copper transfers from the impure electrode to the pure one; some impurities collect as anode sludge. Detailed industrial operation is not required.

The anode loses mass and the cathode gains mass. Copper ions removed at the cathode are replenished at the copper anode, so concentration remains approximately constant in the simple model. This contrasts with an inert anode, where oxygen forms and the blue solution fades.

For copper electroplating, make the object to be coated the cathode, use copper as the anode, and choose a solution containing Cu2+. Clean the object first so the coating adheres. Electroplating can improve appearance or provide a protective surface; the coating metal and intended use determine the benefit.

Check your understandingA student makes a key the anode when trying to copper-plate it. What should change?Think it through, then reveal the answer
The key must be the cathode so Cu2+ gains electrons and deposits on it. Copper supplies the anode, which dissolves to replenish ions.