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Qualitative Analysis

Topic 3 of 4

Identify the gas, not just the bubbles

A named gas needs a specific test and observation.

O-Level 5086 / 5088 (2026) / SEC G3 K326 / K328 (2027)

Identify the gas, not just the bubbles

A named gas needs a specific test and observation.

Six gas tests
GasTestPositive observation
Hydrogen, H2Apply a lighted splint to a small collected sampleA pop
Oxygen, O2Insert a glowing splintSplint relights
Carbon dioxide, CO2Bubble through limewaterWhite precipitate; prolonged excess CO2 can dissolve it
Ammonia, NH3Hold damp red litmus in the gasTurns blue
Chlorine, Cl2Expose damp litmus paper to the gasBleaches; damp blue litmus may first redden
Sulfur dioxide, SO2Use acidified potassium manganate(VII) solutionPurple solution becomes colourless

Litmus must be damp so the gas can dissolve and show its acidic or alkaline effect. Do not identify a gas by smell. Write "effervescence" for bubbles, then describe the confirmatory test. Carbon dioxide extinguishing a flame is less diagnostic than limewater; several gases fail to support combustion.

The sulfur dioxide test is required theory, but candidates are not required to carry out tests involving sulfur dioxide gas in the practical examination. Its colour change reflects reducing behaviour; other reducing substances can also decolourise acidified manganate(VII), so use the experimental context.

Check your understandingA glowing splint is extinguished. Does that identify hydrogen?Think it through, then reveal the answer
No. Hydrogen is tested with a lighted splint and gives a pop. An extinguished glowing splint only shows that the gas did not relight it; it does not uniquely identify the gas.