Skip to notes
Data and Experimental Skills

Topic 3 of 8

Evaluate evidence

Explain limitations and target improvements.

O-Level 5086 / 5088 (2026) / SEC G3 K326 / K328 (2027)

Evaluate evidence and explain the direction of an error

An improvement is useful when it targets a specific limitation.

Different limitations need different responses
IssueEffect on evidenceUseful response
Random variationRepeated results scatter unpredictablyRepeat independent measurements; compare their spread and use a justified mean
Systematic biasResults are displaced consistently, for example by an incorrect calibrationCheck against a suitable standard or correct the apparatus/method; repetition alone does not remove the bias
Uncontrolled variableTwo possible causes change togetherHold that variable constant or design an additional comparison
Limited range or sampleA relationship may be supported only locallyCollect appropriate additional values; restrict the conclusion to the evidence

Accuracy concerns closeness to a valid reference value; precision concerns the closeness of repeated measurements. A tightly grouped set can still be inaccurate. An anomalous point is a reason to investigate the method and repeat a measurement, not permission to remove inconvenient evidence silently. Record an exclusion and its reason.

Worked example

Follow an error through the calculation

An acid in a burette neutralises a known amount of alkali in a flask, in a 1:1 ratio. The burette tip initially contains an air bubble that fills with acid during the titration. What happens to the calculated acid concentration?

  1. Some liquid leaving the graduated barrel fills the tip instead of entering the flask. The recorded titre is larger than the acid volume delivered to the flask.
  2. The known alkali amount still determines the acid amount needed for neutralisation.
  3. Calculated acid concentration = known reacting amount / recorded acid volume. A denominator that is too large gives a concentration that is too low.
Answer

The calculated acid concentration is too low in this arrangement. Fill the tip before taking the initial reading. If the unknown were instead in the flask, the calculation and error direction would need to be reconsidered.

Write evaluation as a causal chain: limitation -> affected measurement -> effect on the calculated result -> targeted improvement. "Human error" and "use better equipment" do not identify what happened. For example, gas escaping before collection lowers measured gas volume; assembling a closed collection system before starting the reaction addresses that loss.

Check your understandingA thermometer reads 2 degrees too high at every temperature. Will averaging five identical readings remove that offset?Think it through, then reveal the answer
No. Averaging reduces the effect of random scatter, not a fixed calibration offset. Check or correct the thermometer against a suitable reference. A temperature difference measured by the same thermometer may cancel a constant offset, provided the offset is truly constant over that range.