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The Periodic Table

Chapter summary

The Periodic Table, at a glance

Explain trends from electrons and structure, then predict the oxides, chlorides and redox behaviour of unfamiliar elements.

A-Level 9476 (2026-2027)

Quick revision

Revisit the essentials, then return to an explanation when you need it.

Five trends, five explanations
ObservationReason
Atomic radius falls across Period 3.Nuclear charge rises with similar inner shielding.
Melting point falls sharply after Si.Giant covalent network changes to discrete molecules.
Oxides change basic → amphoteric → acidic.Bonding and proton-accepting behaviour change across the period.
Group 2 carbonates become more stable down the group.Larger cations polarise carbonate less.
Hydrogen halides become less stable down Group 17.H-X bonds become longer and weaker.

Remember the exceptions and conditions: Mg/Al and P/S ionisation-energy dips; the ionic-radius jump between cation and anion series; white-phosphorus P4; AlCl3 covalent character; phase-dependent PCl5; partial hydrated-ion hydrolysis rather than automatic hydroxide precipitation.

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