Lesson 4 of 10
Half-life and corrected curves
I can infer and sketch exponential decay and use x = x0 exp(-lambda t) for an appropriate population, activity or received source rate.Syllabus
Syllabus 9478, 20(i). Infer and sketch exponential decay and use x = x0 exp(-lambda t) for an appropriate population, activity or received source rate.
I can define half-life and solve problems using suitable quantities, tables or decay curves.Syllabus
Syllabus 9478, 20(j). Define half-life and solve problems using suitable quantities, tables or decay curves.
Make a guess. You are not marked.
Two samples contain the same radioactive nuclide. Sample B has twice as many undecayed nuclei as sample A. How do their half-lives and activities compare?
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Same half-life. B has twice the activity.
Half-life is a property of the nuclide, not of the amount. Activity is lambda times the number of nuclei, so twice the nuclei means twice the decays per second.
Half-life is the time for the expected number of undecayed parent nuclei, or the activity, to fall to half its initial value. For a detector reading, use the source contribution and check that the conditions make it proportional to the decaying population.
For a single unchanged radionuclide, the expected number of undecayed parent nuclei and the activity halve over the same interval. A proportional net source count rate does too when detection conditions remain fixed. Half-life is not the lifetime of every individual nucleus.
After one, two and three half-lives, the remaining fractions are 1/2, 1/4 and 1/8. A few half-lives leave a fraction, not zero. Match time units before comparing: 0.2 min is 12 s, while 2 min is 120 s.
Separate total rate from the source trend
In this supplied model, net source rate starts at 80.0 counts/s and halves every 120 s. Background remains 4.0 counts/s. These are instantaneous expected rates at the named times, not long-window measured averages.
| t / s | Net / counts s-1 | Total / counts s-1 |
|---|---|---|
| 0 | 80 | 84 |
| 120 | 40 | 44 |
| 240 | 20 | 24 |
| 360 | 10 | 14 |
| 480 | 5 | 9 |
Total expected rate approaches the background
The same fixed background is added at every time. Half of the initial raw total is 42 counts/s; that is not the correct halving target for the source. At 120 s the total is 44 counts/s.
Corrected expected rate halves in equal times
The two marked intervals each last 120 s even though the absolute decrease is smaller in the second interval. A proportional corrected rate shares the half-life only while source and detection conditions remain fixed.
Half of the initial raw total is 42 counts/s, but the total at one half-life is 44 counts/s: 40 from the source plus 4 background. Read half-life from the corrected quantity. The falling trend becomes less steep as fewer parents remain; it is not a constant rate of loss.
Worked transfer problem
Count the halvings
A corrected rate decreases from 72 to 9 counts/s in 15 min under fixed detection conditions:
Three half-lives = 15 min
Half-life = 5.0 min
One eighth of the initial rate represents three halvings, not eight. A small negative background-subtracted estimate near zero can arise from fluctuations; it is not negative physical activity.
Try it step by step
Work it out in steps: Number of half-lives, then Fraction of nuclei remaining, then Activity remaining in Bq.
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Problem 1.
Number of half-lives: 24 / 8.0 = 3 half-lives
Fraction of nuclei remaining: Fraction = (1/2)3 = 0.125
Activity remaining in Bq: A = 1200 x 0.125 = 150 Bq
Problem 2.
Number of half-lives: 60 / 15 = 4 half-lives
Fraction of nuclei remaining: Fraction = (1/2)4 = 0.0625
Activity remaining in Bq: A = 5000 x 0.0625 = 313 Bq (3 sf)
Problem 3.
Number of half-lives: 10 / 2.0 = 5 half-lives
Fraction of nuclei remaining: Fraction = (1/2)5 = 0.03125
Activity remaining in Bq: A = 8000 x 0.03125 = 250 Bq
The exponential model relates this shape to decay constant, activity and a logarithmic data fit.
Try it step by step
Work it out in steps: Decay constant lambda = ln 2 / half-life in per hour, then Activity A = A0 e^(-lambda t) in Bq.
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Problem 1.
Decay constant lambda = ln 2 / half-life in per hour: lambda = 0.693 / 10 = 0.0693 per hour
Activity A = A0 e^(-lambda t) in Bq: A = 2000 x e^(-0.0693 x 5.0) = 2000 x 0.707 = 1410 Bq (3 sf)
Problem 2.
Decay constant lambda = ln 2 / half-life in per hour: lambda = 0.693 / 6.0 = 0.116 per hour
Activity A = A0 e^(-lambda t) in Bq: A = 900 x e^(-0.116 x 4.0) = 900 x 0.630 = 567 Bq (3 sf)
Problem 3.
Decay constant lambda = ln 2 / half-life in per hour: lambda = 0.693 / 20 = 0.0347 per hour
Activity A = A0 e^(-lambda t) in Bq: A = 1500 x e^(-0.0347 x 30) = 1500 x 0.354 = 530 Bq (3 sf)
Check your understanding
With fixed detection conditions, a background-corrected rate falls from 72 to 9 counts/s in 15 min. What is the half-life?
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5.0 min.
72 to 36 to 18 to 9 is three half-lives. Therefore each half-life is 15/3 = 5.0 min.