Topic 8 of 9
Mass defect and binding energy
A bound nucleus has less rest mass than its separated nucleons. The corresponding energy difference is the energy required to separate the nucleus completely.
Use mass units consistently
The unified atomic mass unit u is defined as one twelfth of the mass of a neutral carbon-12 atom. For these supplied calculations use 1 u = 1.66 × 10-27 kg. Nucleon number A is dimensionless; it is not an exact mass in u.
Worked conversions
Keep the type of particle in the mass label
A neutral chlorine-37 atom has supplied mass 36.966 u:
= 6.136356 × 10-26 kg
≈ 6.14 × 10-26 kg
This is an atomic mass, including electrons, not a bare nuclear mass. Conversely, a supplied electron mass 9.11 × 10-31 kg is:
me ≈ 5.49 × 10-4 u
The rounded nuclear masses used below contain no orbital electrons. Proton and neutron masses are close to, but not exactly, 1 u.
| Particle or nucleus | Mass / u |
|---|---|
| Proton, mp | 1.00727647 |
| Neutron, mn | 1.00866492 |
| Deuteron, hydrogen-2 nucleus | 2.01355321 |
| Triton, hydrogen-3 nucleus | 3.01550072 |
| Alpha particle, helium-4 nucleus | 4.00150618 |
Convert an energy difference from mass
Mass and energy are equivalent through E = mc2, where c is the speed of electromagnetic waves in vacuum; use the supplied value 3.00 × 108 m/s. A change of rest mass Δm corresponds to an energy change ΔE = Δmc2. For a complete nuclear process, a decrease in total rest mass can supply kinetic energy and radiation while total mass-energy is conserved.
One electronvolt is the energy transferred to a charge of magnitude e through a potential difference of 1 V. With supplied e = 1.60 × 10-19 C:
1 MeV = 1.60 × 10-13 J
Supplied conversion: 1 u c2 = 931.5 MeV
A mass difference of order 10-3 u gives an energy of order 1 MeV, about 10-13 J per nucleus. This is a useful scale check before a precise subtraction. An eV is a unit of energy, not electric potential.
Binding energy is a positive separation energy
For a nucleus with Z protons and A - Z neutrons, the positive mass defect is:
Binding energy = Δmc2
The separated nucleons have greater rest energy. Forming the bound nucleus releases this energy difference; separating it completely requires the same amount to be supplied. A nucleus does not keep radiating its binding energy merely because it remains bound.
The same nucleons have different total rest energies
Binding releases the positive energy difference; complete separation requires that same energy input. The deuteron still contains one proton and one neutron. Its total binding energy is about 2.22 MeV, whereas its binding energy per nucleon is about 1.11 MeV.
Worked deuteron
Total and per-nucleon binding energy
A deuteron contains one proton and one neutron. Using the supplied nuclear masses:
= 0.00238818 u
Binding energy = 0.00238818(931.5)
= 2.22458967 MeV ≈ 2.22 MeV
In joules this is approximately 3.56 × 10-13 J. There are two nucleons, so the binding energy per nucleon is 2.22458967/2 = 1.11229 MeV per nucleon, approximately 1.11 MeV per nucleon.
Keep the mass digits until after subtraction: the defect is much smaller than either original mass. Use one consistent conversion route rather than mixing differently rounded constants. If a problem supplies atomic masses instead, account for electron masses consistently; do not silently mix atomic and nuclear masses.