Full chapter
Bonding and Structure
Why salt, candle wax and copper behave differently: the particles, attractions and moving charges behind their properties.
O-Level 2026 SEC G3 2027. Extensions are labelled Pure only.
One idea connects the chapter
Particles. Attractions. Properties.
Salt melts at a high temperature. Wax softens easily. Copper conducts while solid. The difference starts with what each is made of and what can move.
- Identify the particlesAtoms, molecules or ions?
- Find the attractionsWhat holds them together?
- Explain the propertyWhat needs energy? What moves?
First, identify the particles
An element can contain molecules. A compound can contain ions.
An atom is a single particle of an element. A molecule is a discrete group of atoms joined by covalent bonds. An ion is a charged particle. These describe particles; element, compound and mixture describe what a substance or sample contains.
Atom
Molecule
Ion
Particle symbols, not shell diagrams. Sizes and spacing are not to scale.
| Sample | What makes it different? | Example |
|---|---|---|
| Element | Only one type of atom; cannot be chemically broken into simpler substances. | O2: pairs of oxygen atoms. |
| Compound | Different elements chemically combined in a fixed proportion; separation requires chemical change. | H2O: two hydrogen atoms per oxygen atom. |
| Mixture | Substances together without being chemically combined; proportions can vary and physical separation is possible. | Air: several gases mixed together. |
Check your understandingA diagram contains only identical pairs of oxygen atoms. Element, compound or mixture?Think it through, then reveal the answer
Ionic bonding: transfer, then attraction
Electron transfer creates ions. Attraction between opposite charges holds them together.
A metal atom usually loses outer-shell electrons to form a positive ion. A non-metal atom usually gains electrons to form a negative ion. The resulting ions commonly have the electron arrangement of a noble gas: a full outer shell. The nucleus does not change.
Sodium chloride
Na (2,8,1) loses one electron. Cl (2,8,7) gains that electron.
Magnesium chloride
Mg (2,8,2) loses two electrons. Two Cl atoms each gain one.
- Electron from chlorine
- Electron from the metal
Each bracket shows the ion's full outer shell. The eight electrons on Na+ and Mg2+ were previously in an inner shell. Dots and crosses track origin; all electrons are the same kind of particle.
These groups show the ion ratio, not separate NaCl or MgCl2 molecules. The ions form an extended lattice.
| Starting atom | Electron change | Resulting ion |
|---|---|---|
| Na: 2,8,1 | Loses one electron | Na+: 2,8 |
| Mg: 2,8,2 | Loses two electrons | Mg2+: 2,8 |
| Cl: 2,8,7 | Gains one electron | Cl-: 2,8,8 |
An ionic bond is the strong electrostatic attraction between oppositely charged ions. Na+ and Cl- balance in a 1:1 ratio: NaCl. One Mg2+ needs two Cl- ions: MgCl2. The compound has no overall charge.
Why salt melts high but conducts only when ions move
The attractions explain melting. The mobility of charged particles explains conductivity.
Solid sodium chloride has a giant ionic lattice: a repeating arrangement of positive and negative ions extending throughout the crystal. Each ion attracts surrounding ions of the opposite charge. There are no separate NaCl molecules; its formula gives the simplest ion ratio.
Solid: ions fixed in place
Molten: mobile ions
Dissolved in water: mobile ions
Conductivity needs charged particles that can move. In molten and aqueous sodium chloride, those particles are ions.
The signed bars are electrodes under an applied voltage. Arrows show ion movement, not bond formation. These are simplified slices, not to scale; water molecules and electrode products are omitted.
| Property | Explanation |
|---|---|
| High melting and boiling points | Strong electrostatic attractions act throughout the lattice; much energy is needed to overcome them. |
| Does not conduct when solid | The ions are charged but cannot move through the solid to carry charge. |
| Conducts when molten or dissolved | Mobile ions carry charge through the liquid or solution. |
Check your understandingWhy is "solid salt has no charged particles" an incorrect explanation for its lack of conductivity?Think it through, then reveal the answer
Covalent bonding: count shared pairs
Each shared pair is one bond. Unshared electrons still count towards the outer shell.
Non-metal atoms form a covalent bond by sharing a pair of electrons. Usually each atom contributes one electron. The shared pair counts towards both outer shells, commonly giving a noble-gas arrangement: two electrons for hydrogen, eight for the other atoms shown here.
Each dot or cross is one outer-shell electron. A pair between atoms is shared; a pair beside one atom is a lone pair.
Hydrogen (H2)
- Left H
- Right H
Oxygen (O2)
- Left O
- Right O
Water (H2O)
- Oxygen
- Hydrogens
Methane (CH4)
- Carbon
- Hydrogens
Carbon dioxide (CO2)
- Carbon
- Oxygens
Ammonia (NH3)
- Nitrogen
- Hydrogens
Only outer-shell electrons are shown. Shared electrons count towards both bonded atoms' outer shells. Dots and crosses identify the source atom, not different types of electron.
| Molecule | Shared pairs | Lone pairs |
|---|---|---|
| H2 | One pair between the H atoms: a single bond. | None. |
| O2 | Two pairs between the O atoms: a double bond. | Two on each O. |
| H2O | One pair in each of two O-H bonds. | Two on O. |
| CH4 | One pair in each of four C-H bonds. | None on C. |
| CO2 | Two pairs in each C=O bond: O=C=O. | Two on each O; none on C. |
Worked example
Deduce an unfamiliar diagram: ammonia
Nitrogen has five outer electrons. How are electrons arranged in NH3?
- Nitrogen needs three more electrons around it; each hydrogen needs one.
- Form three shared pairs, one between N and each H. These give three N-H bonds.
- Six electrons surround N in bonds. Its remaining two electrons form one lone pair.
- Check: eight electrons around N, two around each H, and eight outer electrons in total.
Three single N-H bonds and one lone pair on nitrogen. Sharing fills shells without transferring electrons to form ions.
Strong bonds inside; weaker attractions between
Melting a molecular substance separates molecules without breaking them apart.
Methane and iodine have simple molecular structures: many separate molecules. Strong covalent bonds hold atoms together within each molecule. Weaker intermolecular forces attract one molecule to another. These are two different levels of attraction.
Solid iodine
Liquid iodine
- Covalent bond within a molecule
- Attraction between molecules
Melting overcomes enough intermolecular attractions to let the molecules move past one another. It does not break the covalent bonds inside them.
Simplified snapshots, not the measured crystal structure or a simulation. Only a few intermolecular attractions are marked; they are still present in the liquid.
Simple molecular substances generally melt and boil at low temperatures compared with ionic lattices: relatively little energy overcomes their intermolecular forces. Methane is a gas at room temperature, while iodine is a solid. Simple molecular does not mean always gaseous; intermolecular attraction varies between substances.
Their pure solids and liquids generally do not conduct electricity: neutral molecules have no mobile ions or delocalised electrons to carry charge. A solution needs separate consideration: a molecular substance may form ions by reacting with water.
A long molecule is different from a giant network
Compare poly(ethene), diamond, graphite and silicon dioxide.
Poly(ethene) consists of very long covalent molecules called macromolecules. Each chain contains many repeating units. Strong covalent bonds run along a chain, while intermolecular forces act between chains. Longer chains have more opportunities for intermolecular attraction than small molecules such as methane.
Long molecules, separate chains
Example: uncrosslinked poly(ethene). Each CH2 label is a group, not one atom. The straight rows simplify the chain shapes. Cross-linked polymers have different structures.
Poly(ethene) needs more energy to separate its chains than methane needs to separate its small molecules. Heating can soften it without breaking its carbon backbone. It is an electrical insulator because it lacks mobile charged particles. A giant covalent structure, by contrast, has a continuous network of strong covalent bonds rather than separate molecules.
Diamond: four bonds per carbon
Graphite: three bonds per carbon
Silicon dioxide: a repeating network
Original network fragments, not to scale. Bond stubs continue beyond each drawing. Diamond and silica extend in three dimensions; graphite forms extended sheets. The drawings show connections, not measured bond angles.
| Structure | Bonding and arrangement | Properties and uses |
|---|---|---|
| Diamond | Each C bonds to four others in a rigid three-dimensional network. | Very hard: cutting tools. Very high melting point. No mobile electrons: does not conduct. |
| Graphite | Each C bonds to three others in a layer. One electron per C is delocalised. Weak forces act between layers. | Conducts through mobile electrons. Layers slide: soft lubricant. Strong bonds within layers give a very high melting point. |
| Silicon dioxide, SiO2 | Each Si bonds to four O; each O bridges two Si. The formula is a ratio, not a separate molecule. | Hard, high melting point; no mobile charged particles, so does not conduct. A principal constituent of sand. |
Check your understandingHow can graphite be soft and still have a very high melting point?Think it through, then reveal the answer
Metals and alloys: properties from arrangement
Recognize a metal and an alloy, then connect structure to their different behaviour.
Metals generally have high melting and boiling points, conduct heat and electricity, and are malleable: they can be hammered into shape. Most are solids at room temperature. These are general patterns, not rules without exceptions.
In a metal, positive ions occupy a lattice surrounded by delocalised electrons. These electrons are free to move throughout the metal. Metallic bonding is the strong electrostatic attraction between the positive ions and the delocalised electrons.
Positive ions in delocalised electrons
- Positive metal ion
- Delocalised electron
A simplified two-dimensional fragment, not to scale. Plus signs indicate positive charge, not a specified ion charge. The electron count is illustrative.
| Property | Structural explanation |
|---|---|
| High melting point | Much energy is needed to overcome the strong metallic bonding. |
| Electrical conductivity | Delocalised electrons move and carry charge, in both solid and molten metal. |
| Thermal conductivity | Mobile electrons transfer energy rapidly through the metal; lattice vibrations also transfer energy. |
| Malleability | Layers can slide while metallic attraction holds the structure together. |
An alloy is a mixture of a metal with other elements. Brass contains copper and zinc. Stainless steel contains iron and chromium, with other elements depending on its composition. Unlike a compound, an alloy need not have a fixed ratio of elements.
Pure metal: regular layers
Alloy: disrupted layers
A simplified substitutional alloy, not to scale. Other alloys may contain smaller atoms in gaps.
Different-sized atoms disrupt the regular arrangement. Layers slide less easily, so alloys are often harder and less malleable than the pure metal. Their melting behaviour can also differ. The explanation must fit the property: disrupted layers explain hardness, not every possible difference between an alloy and its constituents.
Check your understandingWhy is "the larger atoms are harder" a poor explanation for an alloy being harder?Think it through, then reveal the answer
Work backwards from the evidence
Use several properties together, then explain the particles, attractions and charge carriers.
Worked example
Identify a likely structure
An unknown solid melts at a high temperature. It does not conduct when solid, but conducts after melting. What structure is most likely?
- The high melting point suggests strong attractions extending through the solid.
- The molten material has mobile charged particles.
- The solid lacks mobile charge carriers. That makes a metal unlikely.
- An ionic lattice fits both observations: fixed ions in the solid, mobile ions after melting.
A giant ionic structure. Strong electrostatic attractions require much energy to overcome; ions carry charge only when free to move.
Worked example
Predict a compound from electron arrangement
Element X has electron arrangement 2,8,2. Predict its bonding and formula when it reacts with chlorine.
- X can lose two outer electrons to form X2+, with a full outer shell.
- Each chlorine atom gains one electron to form Cl-.
- Two chloride ions balance one X2+ ion.
XCl2, with ionic bonding between X2+ and Cl-. The electron arrangement helps predict chemical behaviour as well as physical properties.
Check your understandingA pure substance melts at a low temperature and does not conduct as a solid or liquid. Suggest a structure and explain the low melting point.Think it through, then reveal the answer
Bring it together
Quick revision
For every explanation: name the particles, identify the attraction, and say what can move.
| Structure and particles | Melting | Electrical conductivity |
|---|---|---|
| IonicNaClPositive and negative ions | High: strong electrostatic attractions throughout the lattice. | Solid: no. Molten or dissolved: yes, mobile ions. |
| Simple molecularMethane, iodineSeparate molecules | Generally low: weak intermolecular forces are overcome, not covalent bonds. | Pure solid or liquid: generally no mobile charged particles. |
| MacromolecularPoly(ethene)Long covalent moleculesPure only | Softens as chains move past one another; covalent backbones remain intact. | No mobile charged particles. |
| Giant covalentDiamond, graphite, SiO2Atoms in a continuous covalent networkPure only | Very high: strong covalent bonds extend through the structure. | Diamond and SiO2: no. Graphite: yes, delocalised electrons. |
| MetallicCopperPositive ions and delocalised electronsPure only | Generally high: strong attraction between ions and electrons. | Solid and molten: yes, delocalised electrons. |
Three useful corrections
Not conducting? Check whether charged particles can move, not just whether they exist.
Low melting point? Name the weak intermolecular forces, not "weak covalent bonds".
NaCl formula? It gives an ion ratio in a lattice, not a separate molecule.
Scope and references
Your syllabus, covered
These notes cover Chemical Bonding and Structure (topic 3) for Pure Chemistry. Explanations, examples and diagrams are original, checked against the official learning outcomes below.
- 2026 O-Level Pure Chemistry 6092 PDF
Topic 3, pages 12-13. All 17 lettered outcomes are mapped to these notes.
- 2027 SEC G3 Pure Chemistry K324 PDF
Topic 3 has the same content outcomes as the 2026 Pure syllabus.
See how the learning outcomes map to these notes
3.1(a) Form ions by electron transfer
- Electron loss produces a positive ion; electron gain produces a negative ion
- Usual noble-gas electron arrangements and unchanged nuclei
3.1(b) Represent ionic bond formation
- Metal and non-metal examples NaCl and MgCl2
- Dot-and-cross electron accounting, ion charges and formula ratios
3.1(c) Describe a giant ionic lattice
- NaCl as an extended arrangement of oppositely charged ions
- Electrostatic attractions throughout the lattice; lattice drawings are not required
3.1(d) Explain ionic physical properties
- Strong lattice attractions and high melting points
- Fixed ions in a solid; mobile ions when molten or dissolved
3.2(a) Explain a covalent bond
- A shared electron pair
- Usual full outer shells, including the two-electron first shell
3.2(b) Draw the named covalent molecules
- Dot-and-cross diagrams for H2, O2, H2O, CH4 and CO2
- Shared pairs and lone pairs
3.2(c) Deduce another molecule from its electrons
- Count valence electrons, place bonds and check outer shells
- Apply the method to an unfamiliar simple molecule
3.2(d) Connect covalent structure and properties
- Distinguish covalent bonds from intermolecular attractions
- Melting, boiling and electrical conductivity from the actual particles and structure
3.3(a) Describe metallic bonding
- Positive metal ions and delocalised electrons
- Attraction between the ions and the electron sea
3.3(b) Explain the general properties of metals
- High melting and boiling points, with appropriate exceptions
- Malleability and conduction of heat and electricity
3.4(a) Distinguish an element, compound and mixture
- Particle identity and chemical combination
- A molecular element is still an element; a compound need not consist of molecules
3.4(b) Recognise an alloy
- A mixture containing a metal and another element
- Brass and stainless steel
3.4(c) Identify metals and alloys in diagrams
- A regular arrangement in a pure metal
- Different particles in an alloy representation
3.4(d) Explain changed properties of alloys
- Different-sized particles disrupt regular layers
- Relate harder layer movement to strength or hardness
3.4(e) Compare molecular and giant structures
- Simple molecular methane and iodine
- Macromolecular poly(ethene)
- Giant covalent silicon dioxide, diamond and graphite
Strong bonds inside; weaker attractions betweenA long molecule is different from a giant network
3.4(f) Compare diamond and graphite
- Bonding, structure and electrical conductivity
- Cutting action and lubrication; drawing the full structures is not required
3.4(g) Reason from properties to structure and back
- Combine several physical observations rather than one clue
- Use bonding and particle identity to explain properties and avoid unsupported chemical predictions
A long molecule is different from a giant networkWork backwards from the evidence