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Secondary Chemistry Study notes

Bonding and Structure

Why salt, candle wax and copper behave differently: the particles, attractions and moving charges behind their properties.

O-Level 2026 SEC G3 2027. Extensions are labelled Pure only.

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6 topics
  1. Particles and substances

    Distinguish atoms, molecules and ions, then classify elements, compounds and mixtures.

  2. Ionic bonding and properties

    Follow electron transfer, build the idea of a lattice, and explain when ions can carry charge.

  3. Covalent bonding and molecules

    Read shared electron pairs and distinguish bonds within molecules from attractions between them.

  4. Large molecules and giant structures

    Compare polymer chains, diamond, graphite and silicon dioxide through their structures.

    Pure only
  5. Metals and alloys

    Recognize metals and alloys and connect their properties to their arrangement.

  6. Work backwards from the evidence

    Use melting point and conductivity together to identify and explain a likely structure.

Scope and references

Your syllabus, covered

These notes cover Chemical Bonding and Structure (topic 3) for Pure Chemistry. Explanations, examples and diagrams are original, checked against the official learning outcomes below.

See how the learning outcomes map to these notes
  1. 3.1(a) Form ions by electron transfer

    • Electron loss produces a positive ion; electron gain produces a negative ion
    • Usual noble-gas electron arrangements and unchanged nuclei

    Ionic bonding: transfer, then attraction

  2. 3.1(b) Represent ionic bond formation

    • Metal and non-metal examples NaCl and MgCl2
    • Dot-and-cross electron accounting, ion charges and formula ratios

    Ionic bonding: transfer, then attraction

  3. 3.1(c) Describe a giant ionic lattice

    • NaCl as an extended arrangement of oppositely charged ions
    • Electrostatic attractions throughout the lattice; lattice drawings are not required

    Why salt melts high but conducts only when ions move

  4. 3.1(d) Explain ionic physical properties

    • Strong lattice attractions and high melting points
    • Fixed ions in a solid; mobile ions when molten or dissolved

    Why salt melts high but conducts only when ions move

  5. 3.2(a) Explain a covalent bond

    • A shared electron pair
    • Usual full outer shells, including the two-electron first shell

    Covalent bonding: count shared pairs

  6. 3.2(b) Draw the named covalent molecules

    • Dot-and-cross diagrams for H2, O2, H2O, CH4 and CO2
    • Shared pairs and lone pairs

    Covalent bonding: count shared pairs

  7. 3.2(c) Deduce another molecule from its electrons

    • Count valence electrons, place bonds and check outer shells
    • Apply the method to an unfamiliar simple molecule

    Covalent bonding: count shared pairs

  8. 3.2(d) Connect covalent structure and properties

    • Distinguish covalent bonds from intermolecular attractions
    • Melting, boiling and electrical conductivity from the actual particles and structure

    Strong bonds inside; weaker attractions between

  9. 3.3(a) Describe metallic bonding

    • Positive metal ions and delocalised electrons
    • Attraction between the ions and the electron sea

    Metals and alloys: properties from arrangement

  10. 3.3(b) Explain the general properties of metals

    • High melting and boiling points, with appropriate exceptions
    • Malleability and conduction of heat and electricity

    Metals and alloys: properties from arrangement

  11. 3.4(a) Distinguish an element, compound and mixture

    • Particle identity and chemical combination
    • A molecular element is still an element; a compound need not consist of molecules

    First, identify the particles

  12. 3.4(b) Recognise an alloy

    • A mixture containing a metal and another element
    • Brass and stainless steel

    Metals and alloys: properties from arrangement

  13. 3.4(c) Identify metals and alloys in diagrams

    • A regular arrangement in a pure metal
    • Different particles in an alloy representation

    Metals and alloys: properties from arrangement

  14. 3.4(d) Explain changed properties of alloys

    • Different-sized particles disrupt regular layers
    • Relate harder layer movement to strength or hardness

    Metals and alloys: properties from arrangement

  15. 3.4(e) Compare molecular and giant structures

    • Simple molecular methane and iodine
    • Macromolecular poly(ethene)
    • Giant covalent silicon dioxide, diamond and graphite

    Strong bonds inside; weaker attractions betweenA long molecule is different from a giant network

  16. 3.4(f) Compare diamond and graphite

    • Bonding, structure and electrical conductivity
    • Cutting action and lubrication; drawing the full structures is not required

    A long molecule is different from a giant network

  17. 3.4(g) Reason from properties to structure and back

    • Combine several physical observations rather than one clue
    • Use bonding and particle identity to explain properties and avoid unsupported chemical predictions

    A long molecule is different from a giant networkWork backwards from the evidence