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K324 / 2027
Acid-Base Chemistry

Lesson 3 of 7

Classify an oxide by its reactions

Metal/non-metal character suggests a pattern, but exceptions matter.

O-Level 6092 (2026) / SEC G3 K324 (2027)

  • I can classify oxides.Syllabus

    Syllabus K324, 5.1(h). Classify oxides

Classify an oxide by its reactions

Metal/non-metal character suggests a pattern, but exceptions matter.

Four oxide classes
ClassBehaviourExamples
BasicReacts with acids to form salt and waterCuO, MgO: generally metal oxides
AcidicReacts with bases to form salt and waterCO2, SO2: generally non-metal oxides
AmphotericReacts with both acids and strong alkalisAl2O3, ZnO
NeutralDoes not show typical acidic or basic oxide reactionsCO, NO; being a non-metal oxide does not guarantee acidity

For example, CO2(g) + 2NaOH(aq) -> Na2CO3(aq) + H2O(l) with excess alkali shows acidic-oxide behaviour. CuO reacting with an acid shows basic behaviour. An insoluble oxide can still be acidic or basic: classification is not determined by whether it dissolves in water.

Check your understanding

An oxide reacts with hydrochloric acid and also with aqueous sodium hydroxide. How is it classified?

  1. Amphoteric, as it reacts with acids and bases
  2. Neutral, because its acidic and basic sides cancel out
  3. Basic, because it reacts with hydrochloric acid
Show the answer

Amphoteric, as it reacts with acids and bases

A basic oxide reacts with acids only, and an acidic oxide with bases only. Reacting with both is the evidence for an amphoteric oxide, such as zinc oxide or aluminium oxide.

Sort these

Sort the oxides by how they behave with acids and alkalis.

Show the answer

Acidic: SO2 / CO2

Basic: CaO / CuO

Amphoteric: ZnO / Al2O3

Neutral: NO / CO