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Organic Chemistry

Topic 7 of 7

Evaluate plastic use and recycling

Compare what happens to the molecules and to the wider system.

O-Level 5086 / 5088 (2026) / SEC G3 K326 / K328 (2027)

Evaluate plastic use and recycling

Compare what happens to the molecules and to the wider system.

Many plastics are non-biodegradable: natural biological processes do not break them down readily. Persistent waste can harm wildlife through ingestion or entanglement, accumulate in habitats and fragment into small pieces. Burning plastics releases carbon dioxide and, depending on the plastic and conditions, other pollutants. Disposal shifts a problem unless its consequences are considered.

Two recycling routes
RouteWhat happensTrade-off
Physical recyclingSort and clean plastic, cut it into pieces, then melt it into pellets; poly(ethene) is an exampleRetains polymer molecules but mixed materials or contamination can reduce product quality
Chemical recycling by crackingBreak plastic molecules into smaller hydrocarbons that can be used as fuelCan process molecules differently, but requires energy; burning the fuel still releases carbon dioxide
Evaluate a proposed recycling system
DimensionQuestions that matter
SocialIs collection accessible? Are sorting instructions understandable? Are workers and nearby communities affected?
EconomicWhat do collection, transport, sorting and processing cost? Is there a market for the recovered material?
EnvironmentalHow much energy, transport and virgin resource use are avoided or added? What emissions and unrecovered waste remain?

Worked example

Compare two claims

One plan melts clean separated poly(ethene) locally; another ships mixed plastic far away for cracking. Is either always better?

  1. The first may use less processing but depends on clean sorted input and a useful output market.
  2. The second may accept different waste but adds transport and cracking energy.
  3. Compare actual quantities, energy sources, yields and avoided virgin production.
Answer

A justified decision uses evidence across the whole process, rather than assuming the word recycling guarantees a lower impact.

Check your understandingDoes melting poly(ethene) into pellets normally turn it back into ethene?Think it through, then reveal the answer
No. Physical recycling mainly changes shape while retaining long polymer molecules. Recovering monomers requires a chemical depolymerisation route, not ordinary melting.