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Chemical Energetics: Thermochemistry

Chapter summary

Chemical Energetics: Thermochemistry, at a glance

Read reaction energy, measure heat and use supplied cycles without losing signs or stoichiometric factors.

A-Level 8873, revised syllabus (2026-2027)

Quick revision

Revisit the essentials, then return to an explanation when you need it.

Thermochemistry checks
StepRemember
SignExothermic reaction negative; its surroundings gain heat.
One mole of what?Formation: compound; combustion: fuel; neutralisation: water; lattice: solid.
Calorimetryq = mcDeltaT; use all heated solution mass; reaction heat is -q.
Hess cycleReverse arrow → reverse sign; scaled equation → scaled enthalpy.
Bond energiesBroken minus formed, using gas-phase bonds.
Lattice comparisonHigher charges/smaller ions → greater magnitude, more negative formation energy.

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