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Maintaining Air Quality

Topic 3 of 5

Use reactions to reduce harmful emissions

Treat the pollutant before release where possible.

O-Level 6092 (2026) / SEC G3 K324 (2027)

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Use reactions to reduce harmful emissions

Treat the pollutant before release where possible.

A catalytic converter speeds reactions that turn some exhaust pollutants into less harmful products. Carbon monoxide is oxidised to carbon dioxide while nitrogen monoxide can be reduced to nitrogen: 2CO(g) + 2NO(g) -> 2CO2(g) + N2(g). Unburned hydrocarbons can also be oxidised to carbon dioxide and water. The catalyst increases rate; it is not used up overall.

This reduces CO, nitrogen oxides and unburned hydrocarbons, but does not make the exhaust free of environmental impact: carbon dioxide still enters the atmosphere. Nitrogen atoms end up mainly in N2, not in an unspecified harmless gas.

Calcium carbonate has two applications
  1. Neutralise acid already present

    Adding suitable limestone to an acidified lake can consume H+ and reduce acidity. It treats an effect rather than preventing emissions.

  2. Remove sulfur dioxide from flue gas

    Contact exhaust with a limestone-containing treatment system. Acidic sulfur dioxide reacts with calcium carbonate.

  3. Oxidise the captured sulfite

    Further oxidation can form calcium sulfate; the sulfur is retained in a solid product instead of released as SO2.

A simplified sequence is CaCO3(s) + SO2(g) -> CaSO3(s) + CO2(g), followed by 2CaSO3(s) + O2(g) -> 2CaSO4(s). Actual flue-gas systems often use a wet slurry; the equations show the net chemical changes.

Check your understandingIn 2CO + 2NO -> 2CO2 + N2, which reactant is oxidised and which is reduced?Think it through, then reveal the answer
CO gains oxygen and is oxidised; NO loses oxygen and is reduced. The reaction links two pollutant-removal changes through redox.