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Chemical Energetics

Topic 4 of 4

Breaking bonds costs energy; making bonds releases it

The net change depends on both parts of the rearrangement.

O-Level 6092 (2026) / SEC G3 K324 (2027)

Pure only
Pure only

Breaking bonds costs energy; making bonds releases it

The net change depends on both parts of the rearrangement.

Breaking a covalent bond separates atoms that attract one another, so energy must be supplied: it is endothermic. Forming a bond releases energy as atoms become more strongly held together: it is exothermic. A chemical reaction usually does both; never explain combustion by saying that breaking fuel bonds releases energy.

Compare the two energy contributions
  1. Break reactant bonds

    Energy is absorbed.

  2. Form product bonds

    Energy is released.

  3. Compare the amounts

    More released than absorbed gives an exothermic reaction; more absorbed than released gives an endothermic reaction.

Worked example

Explain hydrogen combustion qualitatively

Why can hydrogen reacting with oxygen release energy even though bonds must first break?

  1. H-H and O=O bonds must be broken, requiring energy.
  2. O-H bonds form in water, releasing energy.
  3. The energy released in making product bonds exceeds that needed to break reactant bonds.
Answer

The net change is exothermic. This explanation compares totals, not just whether a bond is strong.

Check your understandingA student says "an endothermic reaction forms no bonds". Correct the statement.Think it through, then reveal the answer
Product bonds may form and release energy, but more energy is absorbed breaking reactant bonds than is released making product bonds. The overall balance is endothermic.