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Chemical Calculations

Topic 1 of 6

Read and construct formulae

Subscripts count atoms; ion charges determine ratios.

O-Level 6092 (2026) / SEC G3 K324 (2027)

Read and construct formulae

Subscripts count atoms; ion charges determine ratios.

An element symbol begins with a capital letter; a second letter is lower-case. Co is cobalt, while CO is carbon monoxide. In H2SO4, one formula unit contains 2 H, 1 S and 4 O atoms. Brackets multiply everything inside: Ca(OH)2 contains 1 Ca, 2 O and 2 H. A coefficient multiplies the entire formula: 3H2O represents six H atoms and three O atoms.

Worked example

From atom counts to a formula

A model molecule contains two nitrogen atoms and four oxygen atoms. What is its formula, and how many oxygen atoms are in three molecules?

  1. Write N and O with the atom counts as subscripts: N2O4.
  2. Three molecules contain 3 x 4 = 12 oxygen atoms. Do not simplify N2O4 to NO2 when the actual atoms in one molecule are specified.
Answer

N2O4; 12 oxygen atoms in three molecules. A coefficient counts complete molecules; a subscript counts atoms within one.

A working symbol and formula bank
FamilySymbols or formulae
Common non-metalsH, C, N, O, F, P, S, Cl, Br, I; elemental gases H2, N2, O2, Cl2
Metals and other elementsLi, Na, K, Mg, Ca, Al, Zn, Fe, Cu, Ag, Pb; Si, He, Ne, Ar
Acids, alkalis and gasesHCl, HNO3, H2SO4, NaOH, Ca(OH)2, NH3, CO, CO2, SO2, NO, NO2, O3
Common salts and reagentsNaCl, MgCl2, CaCO3, CuSO4, AgNO3, Ba(NO3)2, KI, KMnO4
Oxides and organic examplesCaO, MgO, CuO, SiO2; CH4, C2H4, C2H5OH, CH3COOH

An ionic formula must have zero total charge. Al3+ and O2- balance at +6 and -6, giving Al2O3. Mg2+ and NO3- give Mg(NO3)2. Keep a polyatomic ion intact; use brackets only when more than one is needed.

Frequently used ion charges
Positive ionsNegative ions
Na+, K+, Ag+, NH4+Cl-, Br-, I-, OH-, NO3-
Mg2+, Ca2+, Zn2+, Cu2+, Fe2+, Pb2+O2-, CO32-, SO42-
Al3+, Fe3+A Roman numeral gives a metal ion oxidation state; distinguish iron(II) from iron(III).
Check your understandingThe compound is XCl3 and each chloride ion is Cl-. What is the charge on X?Think it through, then reveal the answer
X3+: three chloride ions contribute -3, so one X ion must contribute +3. This is charge balance, not a rule that every metal forms the same charge.