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K223 / K225 / 2027
Qualitative Analysis

Topic 2 of 2

Predict the gas, then prove it

Link each gas to the reaction that makes it, and keep observations separate from conclusions.

SEC G2 Science K223 / K225 (2027)

Predict the gas, then prove it

Link each gas to the reaction that makes it, and record the test as evidence.

Where the three gases come from
ReactionGas producedExample
Reactive metal + dilute acidHydrogenMg(s) + 2HCl(aq) -> MgCl2(aq) + H2(g)
Carbonate + dilute acidCarbon dioxideCaCO3(s) + 2HCl(aq) -> CaCl2(aq) + H2O(l) + CO2(g)
Hydrogen peroxide with a manganese(IV) oxide catalyst, a common laboratory sourceOxygen2H2O2(aq) -> 2H2O(l) + O2(g)

Fizzing, or effervescence, tells you that a gas is being made. It does not tell you which gas. Use what you know about the reaction to predict the gas, then carry out the matching test to prove it. The acid reactions here are the same ones you meet in Acid-Base Chemistry.

Worked example

Identify the gas from an unknown solid

A white solid fizzes when dilute hydrochloric acid is added. How would you show which gas forms?

  1. Effervescence shows that a gas is produced, but bubbles alone do not identify it.
  2. A white solid that fizzes with acid could be a carbonate, giving carbon dioxide, or a metal, giving hydrogen.
  3. Bubble the gas through limewater. A white precipitate confirms carbon dioxide. If there is no precipitate, test a fresh sample of the gas with a lighted splint for hydrogen.
Answer

Record the observations (effervescence; limewater turns milky) separately from the conclusion (the gas is carbon dioxide, so the solid is probably a carbonate).

Check your understandingA gas relights a glowing splint. A student writes "the gas is flammable". Correct the conclusion.Think it through, then reveal the answer
The gas is oxygen. Relighting shows that the gas supports burning; oxygen itself does not burn. A flammable gas such as hydrogen gives a squeaky pop with a lighted splint instead.