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K326 / K328 / 2027
Chemical Energetics

Lesson 1 of 2

Follow the energy transfer

A temperature change is evidence about the surroundings.

O-Level 5086 / 5088 (2026) / SEC G3 K326 / K328 (2027)

  • I can explain exothermic processes.Syllabus

    Syllabus K326 / K328, 9(a). Explain exothermic processes

  • I can explain endothermic processes.Syllabus

    Syllabus K326 / K328, 9(b). Explain endothermic processes

Follow the energy transfer

A temperature change is evidence about the surroundings.

Make a guess. You are not marked.

A solid dissolves in water and the beaker feels cold to touch. What happened to energy?

  1. The dissolving gave out energy, so the water lost heat
  2. The dissolving gave out cold energy to the water
  3. The dissolving took in energy from the water and your hand
Show the answer

The dissolving took in energy from the water and your hand

The process absorbed energy from its surroundings, so the surroundings cooled. That is an endothermic change.

Define the system as the reacting substances and the surroundings as what exchanges energy with them, such as the water, container and air. An exothermic process transfers energy to its surroundings, often as heat; the measured mixture temperature usually rises. An endothermic process takes energy from the surroundings, so their temperature usually falls.

Two useful examples
ProcessObservationEnergy direction
Aqueous sodium hydroxide reacts with hydrochloric acidTemperature risesReaction releases energy to the surroundings
Ammonium nitrate dissolves in waterTemperature fallsDissolving process takes energy from the surroundings

NaOH(aq) + HCl(aq) -> NaCl(aq) + H2O(l) is a neutralisation. Dissolving ammonium nitrate is a physical process with an energy change; an energy transfer does not by itself prove that a new substance has formed.

Check your understanding

A reaction raises the temperature of the surrounding solution from 22 degrees C to 29 degrees C. Is it exothermic or endothermic?

  1. Exothermic, because energy moved from the reacting chemicals to the solution
  2. Endothermic, because the reaction mixture gained energy and grew warmer
  3. Neither, because a temperature rise of 7 degrees C is too small to judge
Show the answer

Exothermic, because energy moved from the reacting chemicals to the solution

The surroundings (the water and thermometer) got warmer, so they gained energy from the reaction. The reacting system lost energy, so delta H is negative.