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Bonding and Structure

Topic 5 of 5

Work backwards from the evidence

Use melting point and conductivity together to identify and explain a likely structure.

O-Level 2026 SEC G3 2027

Work backwards from the evidence

Use several properties together, then explain the particles, attractions and charge carriers.

Worked example

Identify a likely structure

An unknown solid melts at a high temperature. It does not conduct when solid, but conducts after melting. What structure is most likely?

  1. The high melting point suggests strong attractions extending through the solid.
  2. The molten material has mobile charged particles.
  3. The solid lacks mobile charge carriers. That makes a metal unlikely.
  4. An ionic lattice fits both observations: fixed ions in the solid, mobile ions after melting.
Answer

A giant ionic structure. Strong electrostatic attractions require much energy to overcome; ions carry charge only when free to move.

Check your understandingA pure substance melts at a low temperature and does not conduct as a solid or liquid. Suggest a structure and explain the low melting point.Think it through, then reveal the answer
A simple molecular structure is likely. Relatively little energy is needed to overcome weak intermolecular forces. The covalent bonds within the molecules remain intact during melting.