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Chemical Energetics

Chapter summary

Chemical Energetics, at a glance

Track energy through bonds and cycles, then combine enthalpy and entropy to assess thermodynamic feasibility.

A-Level 9476 (2026-2027)

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Revisit the essentials, then return to an explanation when you need it.

Heat gained by the solution is heat lost by the reaction. Hess cycles require identical endpoint states. Bond-energy estimates use gaseous bonds broken minus gaseous bonds formed. The syllabus lattice energy is negative for lattice formation; dissolution uses its reverse plus hydration.

ΔG° = ΔH° - TΔS° with T in K and matching units. Heating favours processes with positive ΔS. A negative standard free-energy change indicates a thermodynamic tendency under standard conditions, not a guaranteed fast or complete reaction.

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