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H2 Chemistry

Chemistry study notes

Atomic Structure

Count particles, build electron configurations and read the evidence in ionisation energies.

A-Level 9476 (2026-2027)

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4 topics
  1. Particles, isotopes and electric fields

    Connect mass and charge to particle counts and beam paths.

  2. Orbitals and their energies

    What s, p and d orbitals mean, how many there are, and their shapes.

  3. Writing electron configurations

    Fill orbitals, account for exceptions and remove the correct electrons from ions.

  4. Ionisation energies as evidence

    Explain an energy change and use large jumps to reconstruct an atom.

Scope and references

Learning outcomes and sources

1. Atomic Structure. Use the outcome map to find the explanation for a particular syllabus requirement.

See the learning outcome map
  1. 1(a) Describe the three subatomic particles.

    • Relative proton, neutron and electron charges
    • Relative masses

    Almost all the mass is in the nucleus

  2. 1(b) Deduce particle-beam behaviour in an electric field.

    • Proton, neutron and electron beam directions
    • Mass and charge comparisons under stated speed conditions

    A beam bends according to charge and mass

  3. 1(c) Locate the mass and charges of an atom.

    • Concentrated nuclear mass and positive charge
    • Negative electrons outside the nucleus

    Almost all the mass is in the nucleus

  4. 1(d) Calculate particle counts in atoms and ions.

    • Proton and nucleon numbers
    • Positive and negative ion charges

    Almost all the mass is in the nucleus

  5. 1(e) Explain nuclear composition and isotopes.

    • (i) Proton number and nucleon number
    • (ii) Same protons, different neutron counts in isotopes

    Almost all the mass is in the nucleus

  6. 1(f) Describe orbital numbers and relative energies.

    • s, p and d subshells for n = 1, 2, 3
    • 4s and 4p
    • One, three and five orbitals in s, p and d

    A shell contains subshells; a subshell contains orbitals

  7. 1(g) Recognise s, p and d orbital shapes.

    • Spherical s
    • Three two-lobed p orientations
    • Five d orbitals including dz2
    • No wave-function mathematics

    Read the shape and orientation of an orbital

  8. 1(h) Write configurations of atoms and ions.

    • Proton number and charge
    • Orbital filling and electron pairing
    • Cr and Cu; 4s removal in transition-metal ions

    Fill orbitals, then remove electrons from the outer shell

  9. 1(i) Explain ionisation-energy differences.

    • Nuclear attraction, shielding, distance
    • Subshell energy and paired-electron repulsion
    • Data Booklet and periodic trends

    Explain the attraction to the electron being removed

  10. 1(j) Deduce configurations from successive ionisation energies.

    • Increasing positive charge
    • Large jumps and shell boundaries
    • Combining energy evidence with particle count or period

    A large jump reveals an inner shell

  11. 1(k) Link successive ionisation energies to periodic position.

    • Main-group outer-electron count
    • Group inference
    • Limits on identifying a period from a partial succession

    A large jump reveals an inner shell